Deep charging & discharging experiment on polyimide films is performed using DECDIS (Satellite Deep Charging & Discharging Simulator).Deep charging processes on samples of various thicknesses under different irradiation conditions are compared. The surface voltage of the polyimide film can reach up to 8000 volts. The experiment initially reveals the deep charging rules of polymer materials, which offers a reference for the study and mitigation of deep charging & discharging effects.